Category: Education
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23.7 Gas Filter Correlation (GFC) spectroscopy
Using filter cells to eliminate wavelengths associated with interfering gases is called positive filtering in the field of spectroscopy. You may think of this as filtering out all the wavelengths the instrument should not “care about.” In order for positive filtering to be completely effective, the analyzer must filter out all wavelengths associated with all interfering species. In some applications, this…
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23.6 Non-dispersive Luft detector spectroscopy
Non-dispersive analysis, while newer in discovery than dispersive analysis (Isaac Newton’s 17th-century prism), has actually seen far earlier application as continuous process analyzers. The basic design was developed during the years 1937-1938 by Dr. Luft and Dr. Lehrer in the laboratories of the German chemical company I.G. Farbenindustrie. By the end of World War II, over…
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23.5 Dispersive spectroscopy
The dispersion of visible light into its constituent colors goes all the way back to the 17th century with Isaac Newton’s experiments, taking a glass prism and generating the characteristic “rainbow” of colors: A modern variation on the theme of a solid glass prism is a thin diffraction grating, causing light of different wavelengths to “bend” as they…
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23.4 Introduction to optical analyses
Light is known to interact with matter in very specific ways, which may be exploited as a means of measuring chemical composition. Either a sample of substance to be analyzed is stimulated into emitting light (optical emission), or made to absorb light from an external source (optical absorption). The specific frequencies (colors) of light obtained from these analyses…
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23.3 Chromatography: Methods, Detectors and Species
Imagine a major marathon race, where hundreds of runners gather in one place to compete. When the starting gun is fired, all the runners begin running the race, starting from the same location (the starting line) at the same time. As the race progresses, the faster runners distance themselves from the slower runners, resulting in…
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23.2 Colorimetric and Potentiometric pH Measurement
pH is the measurement of the hydrogen ion activity in a liquid solution. It is one of the most common forms of analytical measurement in industry, because pH has a great effect on the outcome of many chemical processes. Food processing, water treatment, pharmaceutical production, steam generation (thermal power plants), and alcohol manufacturing are just…
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23.1 Measuring Electrical Conductivity
The electrical conductivity of liquids is an important analytical measurement in many industrial processes. This measurement is one of the more non-specific types of analytical technologies, because it does not discriminate between different conductive substances dissolved in the solution. For this reason, conductivity measurement is found in process applications where the type of conductive substance…
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Chapter 23 Continuous analytical measurement
In the field of industrial instrumentation and process control, the word analyzer generally refers to an instrument tasked with measuring the concentration of some substance, usually mixed with other substances. Unlike the other “bulk” measurement devices for sensing such general variables as pressure, level, temperature, or flow, an analytical device must discriminately detect one specific substance while ignoring all…
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22.10 Insertion flowmeters
This section does not describe a particular type of flowmeter, but rather a design that may be implemented for several different kinds of flow measurement technologies. When the pipe carrying process fluid is large in size, it may be impractical or cost-prohibitive to install a full-diameter flowmeter to measure fluid flow rate. A practical alternative…
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22.9 Change-of-quantity flow measurement
Flow, by definition, is the passage of material from one location to another over time. So far this chapter has explored technologies for measuring flow rate en route from source to destination. However, a completely different method exists for measuring flow rates: measuring how much material has either departed or arrived at the terminal locations…
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22.8 Weighfeeders
A special type flowmeter suited for powdered or granular solids is the weighfeeder. One of the most common weighfeeder designs consists of a conveyor belt with a section supported by rollers coupled to one or more load cells, such that a fixed length of the belt is continuously weighed: The load cell measures the weight of…
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22.7 True mass flowmeters
Many traditional flowmeter technologies respond to the volumetric flow rate of the moving fluid. Velocity-based flowmeters such as magnetic, vortex, turbine, ultrasonic, and optical generate output signals proportional to the speed of fluid molecules and nothing else. This means that if the fluid flowing through one of these flowmeter types were to suddenly become denser (while still…
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22.6 Standardized volumetric flow
The majority of flowmeter technologies operate on the principle of interpreting fluid flow based on the velocity of the fluid. Magnetic, ultrasonic, turbine, and vortex flowmeters are prime examples, where the sensing elements (of each meter type) respond directly to fluid velocity. Translating fluid velocity into volumetric flow is quite simple, following this equation: Where, Q = Volumetric…
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22.5 Positive displacement flowmeters
A positive displacement flowmeter is a cyclic mechanism built to pass a fixed volume of fluid through with every cycle. Every cycle of the meter’s mechanism displaces a precisely defined (“positive”) quantity of fluid, so that a count of the number of mechanism cycles yields a precise quantity for the total fluid volume passed through the flowmeter. Many positive…
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22.4 Velocity-based flowmeters
The Law of Continuity for fluids states that the product of mass density (ρ), cross-sectional pipe area (A) and average velocity (v) must remain constant through any continuous length of pipe: If the density of the fluid is not subject to change as it travels through the pipe (a very good assumption for liquids), we…